Two-step crystallization and solid–solid transitions in binary colloidal mixtures
نویسندگان
چکیده
منابع مشابه
Crystallization kinetics of polydisperse colloidal hard spheres. II. Binary mixtures.
In this paper we present measurements of the crystallization kinetics of binary mixtures of two different sized hard sphere particles. The growth of the Bragg reflections over time were analyzed to yield the crystallite scattering vector, the total amount of crystal, and the average linear crystal size. It was observed that a particle size distribution skewed to higher sized particles has a les...
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The crystallization kinetics of colloidal hard spheres was studied using a special Bragg spectrometer with high sensitivity. In contrast with the classical scenario we observe a two-step nucleation process: the number of crystallites increases slowly at early times, followed by a dramatic reduction at intermediate times, prior to undergoing a rapid increase at late times. We explain these resul...
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We calculate for the first time the full phase diagram of an asymmetric nonadditivehard-sphere mixture. The nonadditivity strongly affects the crystallization and the fluid-fluid phase separation. The global topology of the phase diagram is controlled by an effective size ratio y(eff), while the fluid-solid coexistence scales with the depth of the effective potential well.
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We analyze the phonon spectra of periodic structures formed by two-dimensional mixtures of dipolar colloidal particles. These mixtures display an enormous variety of complex ordered configurations [J. Fornleitner, Soft Matter 4, 480 (2008)], allowing for the systematic investigation of the ensuing phonon spectra and the control of phononic gaps. We show how the shape of the phonon bands and the...
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ژورنال
عنوان ژورنال: Proceedings of the National Academy of Sciences
سال: 2020
ISSN: 0027-8424,1091-6490
DOI: 10.1073/pnas.2008561117